After slogging through the data I've found a few files that weren't copied as they appear to be corrupt. The XMP files weren't moved either, LR may have combined them with the NEF when it created the DNG, but no big loss if it hasn't as I'll have to give them all a house clean anyway.
Problem is that I'm still short on files.
Files Folders
D:\ 14316 671
F:\ 14875 318
Taking into account the 191 that I've already mentioned I'm still looking for 368. JJ's method should have listed everything in that folder, and I then went through all of that confirming the missing files side by side. What the hell is going wrong?
I may have to try a more brute force type approach. Now where's that hammer?