On the photography front as well as
PS Mobile I also use
Format126. I use the official Flickr for iPhone app. mainly because there's loads of them out there and I'm never very far away from a computer connected to the 'net so anything the app. doesn't do I can do on a Mac.
I'm still waiting for the stalled Flickr application that Edd was going to do before I splurge any money on a Flickr application.
For non-photographic purposes I use Skype, Facebook and a great application called
Geocaching.
This last one is a fun little thing that gets you out and about looking for items that other geocachers have placed. You don't have to involve yourself more than simply going around nearby caches, finding them (which can be a little tricky sometimes) and signing a bit of paper. After which you login to the 'site using the app. and update the cach log.
It's like a modern day treasure hunt application. (8+)
Mark