If you used something like Ubuntu (I say that because it's the only one I'm really familiar with!) and a program called
Remastersys you can create your own custom Live CD, possibly removing all but one application, such as Picasa or F-spot and the photo's already added to the library. It'll auto login as a live session (mainly because there is no user setup) and if you have a shortcut on the desktop it is pretty self explanatory how it works...
The "off" button will be in the top right corner as it always is.
Or you could just create a photo CD that'll run on a DVD player or someone's PC.